Materials that shrink when heated

Engineerblogger
Feb 10, 2012

Recent research at the National Institute of Materials Science in Japan on negative thermal expansion (NTE) materials has led to the discovery of alloys exhibiting unexpectedly large thermal contraction.

New research holds promise for applications ranging from high-precision optical components to tooth fillings.

One common reason that people with fillings experience toothache is that their fillings expand at a different rate to the original tooth when, for example, drinking a hot drink. Contrary to intuition, however, not all materials expand when heated—some actually contract. Recent research on these so-called negative thermalexpansion (NTE) materials has led to the discovery of alloys exhibiting unexpectedly large thermal contraction.

Controlling the thermal expansion of composites is important for producing nanometer-scale electronic circuits, as well as the next-generation fuel cells and thermoelectric devices. An ability to combine NTE materials with normal’ materials which expand upon heating ensures a reduction in thermal expansion in a composite material – something that people with tooth fillings would appreciate. An example of such a composite is Invar, an iron-nickel alloy with a uniquely low coefficient of thermal expansion. As a result it is used where high dimensional stability is required, such as precision instruments, clocks or seismic creep gauges.

Koshi Takenaka at the Department of Crystalline Materials Science, Nagoya University in Japan works on NTE materials for practical applications. In the latest issue of Science and Technology of Advanced Materials, he summarizes the physical mechanisms governing NTE with emphasis on recent developments.

Takenaka notes that, “NTE materials will expand our capability of thermal-expansion control, opening a new
paradigm of materials science and technology thermal-expansion-adjustable composites”. One challenge facing the scientist is that the addition of NTE materials to composites leads to undesirable instabilities at interfaces.  New methods for producing stable interfaces between the host composite and NTE compensators are of critical importance. Nevertheless, the so-called ‘one-component’ materials—such as manganese antiperovskites, zirconium vanadates, and hafnium tungstates—exhibiting negligible thermal expansion offer a promising route towards achieving this goal.


Source: National Institute for Materials Science



Additional Information:

• "Negative thermal expansion materials: Technological key for control of thermal expansion" by KoshiTakenaka, Science and Technology of Advanced Materials Vol. 13 (2012) 013001.